Adsorption and micellization behavior of novel gluconamide-type gemini surfactants.

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Abstract Text:

Kenichi Sakai,Shin Umezawa,Mamoru Tamura,Yuichiro Takamatsu,Koji Tsuchiya,Kanjiro Torigoe,Takahiro Ohkubo,Tomokazu Yoshimura,Kunio Esumi,Hideki Sakai,Masahiko Abe,Kenichi Sakai,Shin Umezawa,Mamoru Tamura,Yuichiro Takamatsu,Koji Tsuchiya,Kanjiro Torigoe,Takahiro Ohkubo,Tomokazu Yoshimura,Kunio Esumi,Hideki Sakai,Masahiko Abe,

The adsorption and micellization behavior of novel sugar-based gemini surfactants (N,N(')-dialkyl-N,N(')-digluconamide ethylenediamine, Glu(n)-2-Glu(n), where n is the hydrocarbon chain length of 8, 10 and 12) has been studied on the basis of static/dynamic surface tension, fluorescence, dynamic light scattering (DLS) and cryogenic transmission electron microscope (cryo-TEM) data. The static surface tension of the aqueous Glu(n)-2-Glu(n) solutions measured at the critical micelle concentration (cmc) is observed to be significantly lower than that of the corresponding monomeric surfactants. This suggests that the gemini surfactants, newly synthesized in the current study, are able to form a closely packed monolayer film at the air/aqueous solution interface. The greater ability in the molecular association is supported by the remarkably (approximately 100-200 times) lower cmc of the gemini surfactants compared with the corresponding monomeric ones. With a combination of the fluorescence and DLS data, a structural transformation of the Glu(n)-2-Glu(n) micelles is suggested to occur with an increase in the concentration. The cryo-TEM measurements clearly confirm the formation of worm-like micelles of Glu(12)-2-Glu(12) at the concentration well above the cmc.

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Publishing Authors By Initials

K Sakai,S Umezawa,M Tamura,Y Takamatsu,K Tsuchiya,K Torigoe,T Ohkubo,T Yoshimura,K Esumi,H Sakai,M Abe,K Sakai,S Umezawa,M Tamura,Y Takamatsu,K Tsuchiya,K Torigoe,T Ohkubo,T Yoshimura,K Esumi,H Sakai,M Abe,

For similar abstracts research abstracts see: abstracts research

PUBMED ID PMID:

MEDLINE DATE:

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of colloid and interface science

VOLUME: 318

Page Numbers: 440-8

Journal Abbreviation:

ISSN: 0021-9797

DAY: 6

MONTH: 11

YEAR: 2007

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 43125

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Keywords Mesh Terms:

KEYWORDS:

MESH TERMS:

Chemical & Substance for Abstract: Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. Information

Substance Name:

Registry Number:

Grant and Affiliation Information for Adsorption and micellization behavior of novel gluconamide-type gemini surfactants.

AFFILIATION: Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan.

Country: United States

AGENCY:

GRANT:

ACRONYM:

MEDLINETA: J Colloid Interface Sci

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Adsorption and micellization behavior of novel gluconamide-type gemini surfactants Related Publications

• Alpha1-adrenergic receptor stimulation induces the expression of receptor activator of nuclear factor kappaB ligand gene via protein kinase C and extracellular signal-regulated kinase pathways in MC3T3-E1 osteoblast-like cells.
• An integrated system for medical diagnosis of human facial perception.
• Brain stem arteriovenous malformation with large venous varix.
• Branched poly(lactide) synthesized by enzymatic polymerization: effects of molecular branches and stereochemistry on enzymatic degradation and alkaline hydrolysis.
• DNA microarray analysis of cranial sensory Ganglia identifies genes involved in somatosensation in craniofacial structures including oropharynx related to food intake.
• Development of nonexercise prediction models of maximal oxygen uptake in healthy Japanese young men.
• ERK5 activation inhibits inflammatory responses via peroxisome proliferator-activated receptor delta (PPARdelta) stimulation.
• Emergency stent-grafting for patients over 85 years of age with thoracic aortic rupture.
• Forehead cutaneous blood flow in response to unloaded kaatsu leg exercise: 2324: board #3 june 1 3:30 PM -5:00 PM.
• Induction of DAN/TIR yeast cell wall mannoprotein genes in response to high hydrostatic pressure and low temperature.
• Induction of platelet derived-endothelial cell growth factor in the brain after ischemia.
• Isolation and characterization of salmonid telomeric and centromeric satellite DNA sequences.
• Long-chain fatty acids containing ether linkage. I. The antibacterial and fungicidal activities of some new beta-alkyloxypropionic acids and their methyl esters.
• Magnetic resonance angiography for detection of occlusive neck and proximal vascular diseases.
• MpkA-Dependent and -independent cell wall integrity signaling in Aspergillus nidulans.
• Negative scotopic ERG and photopic ERG ON response impairment in a patient with normal dark adaptation.
• Novel reporter gene expression systems for monitoring activation of the Aspergillus nidulans HOG pathway.
• Odor, information and new cosmetics--the ripple effect on life by aromachology research.
• Perfusion computed tomography for the indication of percutaneous transluminal reconstruction for acute stroke.
• Reliability and frequency specificity of auditory steady-state response detected by phase spectral analysis.
• Role of PKCs and NF-kappaB activation in myocardial inflammation: enemy or ally?
• Strategy for adult aortic coarctation complicated by coronary artery disease.
• Suppression of myofibrillar proteolysis in chick skeletal muscles by alpha-ketoisocaproate.
• Tamoxifen induces masculinization of genetic females and regulates P450 aromatase and Müllerian inhibiting substance mRNA expression in Japanese flounder (Paralichthys olivaceus).
• The short chain fatty acid, butyrate, stimulates MUC2 mucin production in the human colon cancer cell line, LS174T.
• Topology of AspT, the aspartate:alanine antiporter of Tetragenococcus halophilus, determined by site-directed fluorescence labeling.
• Transient receptor potential channel M5 and phospholipaseC-beta2 colocalizing in zebrafish taste receptor cells.
• Treatment methods for spinal cord injury caused by acute type B aortic dissection.
• Validity of Equations for Total and Regional Skeletal Muscle Mass by Ultrasound in Japanese Adolescents: 2092: Board #5 June 1 8:00 AM - 9:30 AM.
• mRNA of MUC2 is stimulated by IL-4, IL-13 or TNF-alpha through a mitogen-activated protein kinase pathway in human colon cancer cells.