A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction.

A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction. Research Abstract Details 

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A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction. Abstract Text:

Falguni Basuli,Brad C Bailey,John Tomaszewski,John C Huffman,Daniel J Mindiola,

One-electron oxidation of the beta-diketiminate titanium(III) bis-neopentyl complex (Nacnac)Ti(CH2tBu)2 (Nacnac = [Ar]NC(Me)CHC(Me)N[Ar], Ar = 2,6-(CHMe2)2C6H3) promotes alpha-abstraction to afford the rare and terminal four-coordinate neopentylidene (Nacnac)Ti=CHtBu(OTf), which was structurally characterized. Alkylidene (Nacnac)Ti=CHtBu(OTf) reacts cleanly with benzophenone and the imine functionality of the Nacnac ligand to afford the corresponding Wittig-type products.

A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction. Publishing Authors By Initials

F Basuli,BC Bailey,J Tomaszewski,JC Huffman,DJ Mindiola,

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A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 125

Page Numbers: 6052-3

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 21

MONTH: May

YEAR: 2003

A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction. Information

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LANGUAGE: eng

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Grant and Affiliation Information for A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction.

AFFILIATION: Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington 47405, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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