A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides.

A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides. Research Abstract Details 

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A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides. Abstract Text:

Michael D Swift,Andrew Sutherland,Michael D Swift,Andrew Sutherland,Michael D Swift,Andrew Sutherland,

A one-pot tandem palladium(II)-catalyzed aza-Claisen rearrangement and ring closing metathesis process has been developed for the efficient synthesis of cyclic allylic trichloroacetamides. The use of chiral Pd(II) catalysts such as (S)-COP-Cl during the rearrangement stage results in the preparation of these compounds in excellent yields and in high enantiomeric excess.

A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides. Publishing Authors By Initials

MD Swift,A Sutherland,MD Swift,A Sutherland,MD Swift,A Sutherland,

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A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Organic letters

VOLUME: 9

Page Numbers: 5239-42

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 9

MONTH: 11

YEAR: 2007

A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides. Information

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LANGUAGE: eng

NlmUniqueID: 100890393

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Grant and Affiliation Information for A tandem aza-claisen rearrangement and ring closing metathesis reaction for the synthesis of cyclic allylic trichloroacetamides.

AFFILIATION: WestCHEM, Department of Chemistry, The Joseph Black Building, University of Glasgow, Glasgow, UK G12 8QQ.

Country: United States

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