A surprisingly stable homoleptic Pd(0)(4) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd(4)](2+) chain sandwich complex.
A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands. Publishing Authors By Initials
A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands. Journal Published:
PUBLICATION TYPE: Journal Article
Journal: Chemical communications (Cambridge, England)
VOLUME:
Page Numbers: 477-9
Journal Abbreviation: Chem. Commun. (Camb.)
ISSN: 1359-7345
DAY: 13
MONTH: 11
YEAR: 2007
A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands. Information
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LANGUAGE: eng
NlmUniqueID: 9610838
A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands. Keywords Mesh Terms:
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Grant and Affiliation Information for A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands.
AFFILIATION: Department of Applied Chemistry, Osaka University, & PRESTO, Japan Science and Technology Agency (JST), Suita, Osaka, 565-0871, Japan. tetsu@chem.eng.osaka-u.ac.jp.
Country: England
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MEDLINETA: Chem Commun (Camb)
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