A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation.

A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation. Research Abstract Details 

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A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation. Abstract Text:

Jing Liu,Junlin Yan,Xuanwei Yuan,Kaiqiang Liu,Junxia Peng,Yu Fang,Jing Liu,Junlin Yan,Xuanwei Yuan,Kaiqiang Liu,Junxia Peng,Yu Fang,

A novel low-molecular-mass gelator containing a redox-active ferrocenyl group, cholesteryl glycinate ferrocenoylamide (CGF), was intentionally designed and prepared. It was demonstrated that the gelator gels 13 out of the 45 solvents tested. Scanning electron microscopy (SEM) measurements revealed that the gelator self-assembled into different supramolecular network structures in different gels. Chemical oxidation of the ferrocenyl residue resulted in phase transition of the gel from gel state to solution state. FTIR and (1)H NMR spectroscopy studies revealed that hydrogen bonding between the gelator molecules in the gel was one of the main driving forces for the formation of the gels.

A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation. Publishing Authors By Initials

J Liu,J Yan,X Yuan,K Liu,J Peng,Y Fang,J Liu,J Yan,X Yuan,K Liu,J Peng,Y Fang,

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A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of colloid and interface science

VOLUME: 318

Page Numbers: 397-404

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ISSN: 0021-9797

DAY: 19

MONTH: 11

YEAR: 2007

A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation. Information

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LANGUAGE: eng

NlmUniqueID: 43125

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Grant and Affiliation Information for A novel low-molecular-mass gelator with a redox active ferrocenyl group: Tuning gel formation by oxidation.

AFFILIATION: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062, People's Republic of China.

Country: United States

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MEDLINETA: J Colloid Interface Sci

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