A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand.

A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand. Research Abstract Details 

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A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand. Abstract Text:

Junhua Luo,Yusheng Zhao,Hongwu Xu,Tiffany L Kinnibrugh,Dali Yang,Tatiana V Timofeeva,Luke L Daemen,Jianzhong Zhang,Wei Bao,Joe D Thompson,Robert P Currier,Junhua Luo,Yusheng Zhao,Hongwu Xu,Tiffany L Kinnibrugh,Dali Yang,Tatiana V Timofeeva,Luke L Daemen,Jianzhong Zhang,Wei Bao,Joe D Thompson,Robert P Currier,

A novel cobalt(II)-organic framework, [Co2(OH)(3,4-PBC)3]n (I), has been acquired by the reaction of CoO with an unsymmetrical pyridylbenzoate ligand, 3-pyrid-4-ylbenzoic acid (3,4-PBC). Single-crystal X-ray diffraction studies reveal that it is comprised of [CoII4(mu3-OH)2] clusters linked by the unsymmetrical ligand 3,4-PBC, forming a novel helical double-layered metal-organic architecture. A significant overall antiferromagnetic behavior has been observed for this compound.

A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand. Publishing Authors By Initials

J Luo,Y Zhao,H Xu,TL Kinnibrugh,D Yang,TV Timofeeva,LL Daemen,J Zhang,W Bao,JD Thompson,RP Currier,J Luo,Y Zhao,H Xu,TL Kinnibrugh,D Yang,TV Timofeeva,LL Daemen,J Zhang,W Bao,JD Thompson,RP Currier,

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A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Inorganic chemistry

VOLUME: 46

Page Numbers: 9021-3

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ISSN: 0020-1669

DAY: 22

MONTH: 09

YEAR: 2007

A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand. Information

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LANGUAGE: eng

NlmUniqueID: 366543

A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand. Keywords Mesh Terms:

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Grant and Affiliation Information for A novel helical double-layered cobalt(II)-organic framework with tetranuclear [Co4(mu3-OH)2] clusters linked by an unsymmetrical pyridylbenzoate ligand.

AFFILIATION: Los Alamos Neutron Science Center, Earth and Environmental Sciences Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA. jhluo@lanl.gov

Country: United States

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MEDLINETA: Inorg Chem

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