A facile approach to a d4 RuN: moiety.

A facile approach to a d4 RuN: moiety. Research Abstract Details 

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A facile approach to a d4 RuN: moiety. Abstract Text:

Amy Walstrom,Maren Pink,Xiaofan Yang,John Tomaszewski,Mu-Hyun Baik,Kenneth G Caulton,

Replacement of chloride in (PNP)RuCl, PNP = (tBu2PCH2SiMe2)2N, by Me3SiN3 gives a pre-redox adduct that, already at -30 degrees C, releases N2 to produce the mononuclear nonplanar Ru(IV) nitride (PNP)RuN, characterized by spectroscopic and X-ray methods. DFT calculations show the planar structure to be only 1.6 kcal/mol less stable, which explains the time-averaged simplicity of the 1H NMR spectrum, as well as the large vibrational amplitude of the nitride ligand.

A facile approach to a d4 RuN: moiety. Publishing Authors By Initials

A Walstrom,M Pink,X Yang,J Tomaszewski,MH Baik,KG Caulton,

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A facile approach to a d4 RuN: moiety. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 5330-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 20

MONTH: Apr

YEAR: 2005

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LANGUAGE: eng

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AFFILIATION: Department of Chemistry, Indiana University, 800 East Kirkwood Avenue, Room A250B, Bloomington, Indiana 47405-7102, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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