A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes.

A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Research Abstract Details 

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A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Abstract Text:

Christopher G Oliveri,Jungseok Heo,Sonbinh T Nguyen,Chad A Mirkin,Zdzislaw Wawrzak,

We report a highly convergent and modular approach for the synthesis of dissymmetric cofacial porphyrin complexes, which is based upon the weak-link approach to supramolecular coordination chemistry. Specifically, we have utilized a halide-induced ligand rearrangement reaction, which is capable of providing heteroligated mixed-metal porphyrin complexes in quantitative yield. Significantly, the adoption of a coordination chemistry based approach for the synthesis of these complexes allows for facile in situ regulation of the porphyrin-porphyrin interactions through the addition of external chemical stimuli.

A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Publishing Authors By Initials

CG Oliveri,J Heo,ST Nguyen,CA Mirkin,Z Wawrzak,

For similar heterocyclic compounds: heterocyclic compounds, 1-ring: azoles: pyrroles: tetrapyrroles: porphyrins research abstracts see: heterocyclic compounds: heterocyclic compounds, 1-ring: azoles: pyrroles: tetrapyrroles: porphyrins research

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A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Inorganic chemistry

VOLUME: 46

Page Numbers: 7716-8

Journal Abbreviation:

ISSN: 0020-1669

DAY: 14

MONTH: 08

YEAR: 2007

A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Information

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LANGUAGE: eng

NlmUniqueID: 366543

A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Keywords Mesh Terms:

KEYWORDS: Porphyrins

MESH TERMS: chemistry

Chemical & Substance for Abstract: A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes. Information

Substance Name: Porphyrins

Registry Number: 0

Grant and Affiliation Information for A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes.

AFFILIATION: Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.

Country: United States

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MEDLINETA: Inorg Chem

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