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A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols.

A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Research Abstract Details 

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  • A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Abstract Text:

    hae-jo kimHae-Jo Kim,woosung kimWoosung Kim,alan j loughAlan J Lough,b moon kimB Moon Kim,jik chinJik Chin,

    A cobalt(III)-salen complex (3) with an axial substituent on the diamine backbone has been synthesized. Crystal structure reveals that the axial substituent (p-nitrophenyl group) is positioned in close proximity to the metal binding site. The stereoselectivity of the cobalt complex for binding amino alcohols increases with increasing steric bulk of the amino alcohol from alaninol (2.9) to valinol (6.2) and t-leucinol (36.0).

    A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Publishing Authors By Initials

    hj kimHJ Kim,w kimW Kim,aj loughAJ Lough,bm kimBM Kim,j chinJ Chin,

    For similar abstracts research abstracts see: abstracts research

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    A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Journal of the American Chemical Society

    VOLUME: 127

    Page Numbers: 16776-7

    Journal Abbreviation: J. Am. Chem. Soc.

    ISSN: 0002-7863

    DAY: 7

    MONTH: Dec

    YEAR: 2005

    A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Information

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    LANGUAGE: eng

    NlmUniqueID: 7503056

    A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Keywords Mesh Terms:

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    Grant and Affiliation Information for A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols.

    AFFILIATION: Department of Chemistry, University of Toronto, Canada.

    Country: United States

    United States Research PublicationUnited States Research Publication

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    MEDLINETA: J Am Chem Soc

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