A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols.
A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Research Abstract Details
A cobalt(III)-salen complex (3) with an axial substituent on the diamine backbone has been synthesized. Crystal structure reveals that the axial substituent (p-nitrophenyl group) is positioned in close proximity to the metal binding site. The stereoselectivity of the cobalt complex for binding amino alcohols increases with increasing steric bulk of the amino alcohol from alaninol (2.9) to valinol (6.2) and t-leucinol (36.0).
A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Publishing Authors By Initials
A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Journal Published:
PUBLICATION TYPE: Journal Article
Journal: Journal of the American Chemical Society
VOLUME: 127
Page Numbers: 16776-7
Journal Abbreviation: J. Am. Chem. Soc.
ISSN: 0002-7863
DAY: 7
MONTH: Dec
YEAR: 2005
A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols. Information
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LANGUAGE: eng
NlmUniqueID: 7503056
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Grant and Affiliation Information for A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcohols.
AFFILIATION: Department of Chemistry, University of Toronto, Canada.
Country: United States
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MEDLINETA: J Am Chem Soc
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