A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene.

A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Research Abstract Details 

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A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Abstract Text:

Anna E Cherian,Jeffrey M Rose,Emil B Lobkovsky,Geoffrey W Coates,

An isomerically pure, C2-symmetric Ni(II) complex was synthesized and found to be living for propylene polymerization. The regioselectivity of the catalyst varied greatly with reaction temperature, with regioregular, highly isotactic polypropylene (PP) produced at low temperatures, and regioirregular PP produced at high temperatures. Regioblock PP was formed by changing the reaction temperature during the polymerization.

A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Publishing Authors By Initials

AE Cherian,JM Rose,EB Lobkovsky,GW Coates,

For similar organic chemicals: organometallic compounds research abstracts see: organic chemicals: organometallic compounds research

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A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 13770-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 12

MONTH: Oct

YEAR: 2005

A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Keywords Mesh Terms:

KEYWORDS: Organometallic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. Information

Substance Name: Nickel

Registry Number: 7440-02-0

Grant and Affiliation Information for A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene.

AFFILIATION: Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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