[2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands.

[2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands. Research Abstract Details 

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[2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands. Abstract Text:

Barry A Blight,Xu Wei,James A Wisner,Michael C Jennings,Barry A Blight,Xu Wei,James A Wisner,Michael C Jennings,Barry A Blight,Xu Wei,James A Wisner,Michael C Jennings,Barry A Blight,Xu Wei,James A Wisner,Michael C Jennings,

A Pd(Py)(2)(SCN)(2) complex is shown to form a [2]pseudorotaxane complex with a macrocyclic tetralactam, which binds in the solid state through an unexpected complexation geometry. The intermolecular complexation is further applied to template the formation of a [2]rotaxane. The interlocked product acts as a degenerate molecular shuttle in solution, which is consistent with the co-conformation observed in the solid state.

[2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands. Publishing Authors By Initials

BA Blight,X Wei,JA Wisner,MC Jennings,BA Blight,X Wei,JA Wisner,MC Jennings,BA Blight,X Wei,JA Wisner,MC Jennings,BA Blight,X Wei,JA Wisner,MC Jennings,

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[2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 46

Page Numbers: 8445-7

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ISSN: 0020-1669

DAY: 19

MONTH: 09

YEAR: 2007

[2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands. Information

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LANGUAGE: eng

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Grant and Affiliation Information for [2]Pseudorotaxane and [2]rotaxane molecular shuttles: self-assembly through second-sphere coordination of thiocyanate ligands.

AFFILIATION: Department of Chemistry, The University of Western Ontario, 1151 Richmond Street, London, Ontario N6A 5B7, Canada.

Country: United States

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MEDLINETA: Inorg Chem

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