{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)--an ionic compound containing molecular bromine.

{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)--an ionic compound containing molecular bromine. Research Abstract Details 

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{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)--an ionic compound containing molecular bromine. Abstract Text:

Dark green cuboid-shaped crystals of the composition {[P(o-tolyl) 3]Br} 2[Cu 2Br 6](Br 2) are obtained by the reaction of P(o-tolyl) 3 and CuBr 2 with Br 2 in the ionic liquid [NMeBu 3][N(Tf) 2]. The bromocuprate crystallizes triclinic [space group P1; Z = 1; a = 10.667(2) A; b = 10.695(2) A; c = 11.582(2) A; alpha = 74.42(3) degrees ; beta = 75.64(3) degrees ; and gamma = 85.68(3) degrees ]. The title compound is constituted of {[P(o-tolyl) 3]Br} (+) cations and [Cu 2Br 6] (2-) anions and contains molecular dibromine [d Br-Br = 2.341(1) A]. The latter is verified by thermogravimetry and mass spectrometry.

{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)--an ionic compound containing molecular bromine. Publishing Authors By Initials

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{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)--an ionic compound containing molecular bromine. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 47

Page Numbers: 3084-7

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ISSN: 0020-1669

DAY: 5

MONTH: 03

YEAR: 2008

{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)--an ionic compound containing molecular bromine. Information

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LANGUAGE: eng

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AFFILIATION: Institute of Inorganic Chemistry, University of Karlsruhe (TH), Engesserstrasse 15, Karlsruhe, Germany.

Country: United States

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MEDLINETA: Inorg Chem

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