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| Peptide Forum Peptide Forum. Ask and discuss questions on peptide protocols, custom peptide synthesis, peptide identification and peptide sequencing. |
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#1
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| Why is free rotation around the N-C? bond of a peptide not allowed? A Steric clash from amino side chains prevents rotation from occurring. B sp-hybridization due to the partial double bond character prevents rotation from occurring. C Protein tertiary structure prevents rotation from occurring. D The free electron pair of the nitrogen atom repulses the C? atom, preventing rotation from occurring. E Free rotation around the N-C? bond of a peptide is allowed. |
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#2
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| Ans (B) The partial double bond nature of the peptide bond means that there is not free rotation about the C -- N bond |
| Tags |
| allowed , bond , free , ncandalpha , peptide , rotation |
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