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Oppenauer Oxidation - Other bases?

Oppenauer Oxidation - Other bases? - Chemistry Forum

Oppenauer Oxidation - Other bases? - Chemistry Forum. Discuss chemical reactions, chemistry.


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Old 02-12-2004, 11:52 AM
Darren Rhodes
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Default Oppenauer Oxidation - Other bases?



Aluminium butoxide is given in references for the Oppenauer oxidation - has
anyone had any experience of using other bases?

Darren.


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Old 02-12-2004, 04:17 PM
Mohammed Farooq
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Default Oppenauer Oxidation - Other bases?

"Darren Rhodes" <[Only registered users see links. ]> wrote in message news:<c0fpdi$65s$[Only registered users see links. ]>...

Two references by that might be of interest:
1. Krohn, K. et al.: Zirconium Alkoxide-catalysed Oppenauer Oxidation
using Chloral as the Hydride Acceptor. Synthesis; 1996, pp. 1341-1344
2. Tetrahedron Letters (1987), 28(7), 769-72, uses magnesium
alkoxides.
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Old 02-12-2004, 04:56 PM
Darren Rhodes
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Default Oppenauer Oxidation - Other bases?


"Mohammed Farooq" <[Only registered users see links. ]> wrote in message
news:66756669.0402120817.5de4ace0@posting.google.c om...
news:<c0fpdi$65s$[Only registered users see links. ]>...
has

They certainly are of interest. Thanks ... I'm currently looking at a
ruthenium catalyst. Darren.



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